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P−P Condensation and P−N/P−P Bond Metathesis: Facile Synthesis of Cationic Tri‐ and Tetraphosphanes

[L(C) (R)P((PhP)(2)C(2)H(4))][OTf] (4 a,b[OTf]) and [L(C) (iPr)P(PPh(2))(2)][OTf] (5 b[OTf]) were prepared from the reaction of imidazoliumyl‐substituted dipyrazolylphosphane triflate salts [L(C) (R)P(pyr)(2)][OTf] (3 a,b[OTf]; a: R=Me, b=iPr; L(C) (R)=1,3‐dialkyl‐4,5‐dimethylimidazol‐2‐yl; pyr=3,5‐...

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Detalles Bibliográficos
Autores principales: Taube, Clemens, Schwedtmann, Kai, Noikham, Medena, Somsook, Ekasith, Hennersdorf, Felix, Wolf, Robert, Weigand, Jan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7065231/
https://www.ncbi.nlm.nih.gov/pubmed/31705596
http://dx.doi.org/10.1002/anie.201911483