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Controlled scrambling reactions to polyphosphanes via bond metathesis reactions

Triphosphanes R′(2)PP(R)PR′(2) (9a,c: R = Py; 9b R = BTz), 1,3-diphenyl-2-pyridyl-triphospholane 9d and pentaphospholanes (RP)(5) (13: R = Py; 18: R = BTz) are obtained in high yield of up to 98% from the reaction of dipyrazolylphosphanes RPpyr(2) (5: R = Py; 6: R = BTz; pyr = 1,3-dimethylpyrazolyl)...

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Detalles Bibliográficos
Autores principales: Schoemaker, Robin, Schwedtmann, Kai, Franconetti, Antonio, Frontera, Antonio, Hennersdorf, Felix, Weigand, Jan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7066665/
https://www.ncbi.nlm.nih.gov/pubmed/32190255
http://dx.doi.org/10.1039/c9sc04501e