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Unravelling the mechanism of cobalt-catalysed remote C–H nitration of 8-aminoquinolinamides and expansion of substrate scope towards 1-naphthylpicolinamide

Previously, an unexpected Co-catalysed remote C–H nitration of 8-aminoquinolinamide compounds was developed. This report provided a novel reactivity for Co which was assumed to proceed through the mechanistic pathway already known for analogous Cu-catalysed remote couplings of the same substrates. I...

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Detalles Bibliográficos
Autores principales: Chu, Melody, Planas, Oriol, Company, Anna, Ribas, Xavi, Hamilton, Alex, Whiteoak, Christopher J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7067239/
https://www.ncbi.nlm.nih.gov/pubmed/32190273
http://dx.doi.org/10.1039/c9sc05076k