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Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides

A series of unique C(2)P(3)-ring compounds [(ADC(Ar))P(3)] (ADC(Ar) = ArC{(DippN)C}(2); Dipp = 2,6-iPr(2)C(6)H(3); Ar = Ph 4a, 3-MeC(6)H(4)4b, 4-MeC(6)H(4)4c, and 4-Me(2)NC(6)H(4)4d) are readily accessible in an almost quantitative yield by the direct functionalization of white phosphorus (P(4)) wit...

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Detalles Bibliográficos
Autores principales: Rottschäfer, Dennis, Blomeyer, Sebastian, Neumann, Beate, Stammler, Hans-Georg, Ghadwal, Rajendra S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7069227/
https://www.ncbi.nlm.nih.gov/pubmed/32206256
http://dx.doi.org/10.1039/c9sc04441h