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Interconversion and reactivity of manganese silyl, silylene, and silene complexes

Manganese disilyl hydride complexes [(dmpe)(2)MnH(SiH(2)R)(2)] (4(Ph): R = Ph, 4(Bu): R = (n)Bu) reacted with ethylene to form silene hydride complexes [(dmpe)(2)MnH(RHSi[double bond, length as m-dash]CHMe)] (6(Ph,H): R = Ph, 6(Bu,H): R = (n)Bu). Compounds 6(R,H) reacted with a second equivalent of...

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Detalles Bibliográficos
Autores principales: Price, Jeffrey S., Emslie, David J. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7069235/
https://www.ncbi.nlm.nih.gov/pubmed/32206252
http://dx.doi.org/10.1039/c9sc04513a