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Interconversion and reactivity of manganese silyl, silylene, and silene complexes
Manganese disilyl hydride complexes [(dmpe)(2)MnH(SiH(2)R)(2)] (4(Ph): R = Ph, 4(Bu): R = (n)Bu) reacted with ethylene to form silene hydride complexes [(dmpe)(2)MnH(RHSi[double bond, length as m-dash]CHMe)] (6(Ph,H): R = Ph, 6(Bu,H): R = (n)Bu). Compounds 6(R,H) reacted with a second equivalent of...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7069235/ https://www.ncbi.nlm.nih.gov/pubmed/32206252 http://dx.doi.org/10.1039/c9sc04513a |