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Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex

A dicopper complex featuring a symmetrically bridging nitrile ligand and supported by a binucleating naphthyridine-based ligand, [Cu(2)(μ-η(1):η(1)-MeCN)DPFN](NTf(2))(2), was treated with phosphaalkynes (RC[triple bond, length as m-dash]P, isoelectronic analogues of nitriles) to yield dicopper compl...

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Detalles Bibliográficos
Autores principales: Nicolay, Amélie, Ziegler, Micah S., Small, David W., Grünbauer, Rebecca, Scheer, Manfred, Tilley, T. Don
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7069238/
https://www.ncbi.nlm.nih.gov/pubmed/32206279
http://dx.doi.org/10.1039/c9sc05835d