Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling

The addition of Lewis bases to a cyclic (alkyl)(amino)carbene (CAAC)-supported dihydroboron triflate yields the mixed doubly base-stabilised dihydroboryl cations [(CAAC)BH(2)L](+). Of these, [(CAAC)(2)BH(2)]OTf (OTf = triflate) underwent facile two-electron reduction with KC(8) owing to a 1,2-hydrid...

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Detalles Bibliográficos
Autores principales: Hagspiel, Stephan, Arrowsmith, Merle, Fantuzzi, Felipe, Hermann, Alexander, Paprocki, Valerie, Drescher, Regina, Krummenacher, Ivo, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7069503/
https://www.ncbi.nlm.nih.gov/pubmed/32206272
http://dx.doi.org/10.1039/c9sc05026d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7069503/
https://www.ncbi.nlm.nih.gov/pubmed/32206272
http://dx.doi.org/10.1039/c9sc05026d

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