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Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
The addition of Lewis bases to a cyclic (alkyl)(amino)carbene (CAAC)-supported dihydroboron triflate yields the mixed doubly base-stabilised dihydroboryl cations [(CAAC)BH(2)L](+). Of these, [(CAAC)(2)BH(2)]OTf (OTf = triflate) underwent facile two-electron reduction with KC(8) owing to a 1,2-hydrid...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7069503/ https://www.ncbi.nlm.nih.gov/pubmed/32206272 http://dx.doi.org/10.1039/c9sc05026d |