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Rh(ii)-catalyzed branch-selective C–H alkylation of aryl sulfonamides with vinylsilanes
Rhodium(ii)-catalyzed unusual branch-selective ortho-C–H alkylation of aryl sulfonamides with vinylsilanes was achieved using an 8-aminoquinoline directing group. Notably, the para-substituted aryl sulfonamides gave mono-(branched)alkylated products exclusively without the formation of any double C–...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7069504/ https://www.ncbi.nlm.nih.gov/pubmed/32206270 http://dx.doi.org/10.1039/c9sc04308j |