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Wavelength-gated photoreversible polymerization and topology control

We exploit the wavelength dependence of [2 + 2] photocycloadditions and -reversions of styrylpyrene to exert unprecedented control over the photoreversible polymerization and topology of telechelic building blocks. Blue light (λ(max) = 460 nm) initiates a catalyst-free polymerization yielding high m...

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Detalles Bibliográficos
Autores principales: Frisch, Hendrik, Mundsinger, Kai, Poad, Berwyck L. J., Blanksby, Stephen J., Barner-Kowollik, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7069517/
https://www.ncbi.nlm.nih.gov/pubmed/32206267
http://dx.doi.org/10.1039/c9sc05381f