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Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage

Two flexible subcomponents, namely tris(4-formylphenyl)phosphate and tris(2-aminoethyl)amine, are assembled into a tetrapodal [4 + 4] cage depending on the solvent effect. Single-crystal structure analysis reveals that the caivity is surrounded by four phosphate uints. Good selectivity of CO(2) adso...

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Detalles Bibliográficos
Autores principales: Feng, Gen-Feng, Geng, Jiao, Feng, Fan-Da, Huang, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070053/
https://www.ncbi.nlm.nih.gov/pubmed/32170278
http://dx.doi.org/10.1038/s41598-020-61813-6