Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage

Two flexible subcomponents, namely tris(4-formylphenyl)phosphate and tris(2-aminoethyl)amine, are assembled into a tetrapodal [4 + 4] cage depending on the solvent effect. Single-crystal structure analysis reveals that the caivity is surrounded by four phosphate uints. Good selectivity of CO(2) adso...

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Autores principales: Feng, Gen-Feng, Geng, Jiao, Feng, Fan-Da, Huang, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070053/
https://www.ncbi.nlm.nih.gov/pubmed/32170278
http://dx.doi.org/10.1038/s41598-020-61813-6
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author Feng, Gen-Feng
Geng, Jiao
Feng, Fan-Da
Huang, Wei
author_facet Feng, Gen-Feng
Geng, Jiao
Feng, Fan-Da
Huang, Wei
author_sort Feng, Gen-Feng
collection PubMed
description Two flexible subcomponents, namely tris(4-formylphenyl)phosphate and tris(2-aminoethyl)amine, are assembled into a tetrapodal [4 + 4] cage depending on the solvent effect. Single-crystal structure analysis reveals that the caivity is surrounded by four phosphate uints. Good selectivity of CO(2) adsorption over CH(4) is demonstrated by the gas adsorption experiment.
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spelling pubmed-70700532020-03-22 Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage Feng, Gen-Feng Geng, Jiao Feng, Fan-Da Huang, Wei Sci Rep Article Two flexible subcomponents, namely tris(4-formylphenyl)phosphate and tris(2-aminoethyl)amine, are assembled into a tetrapodal [4 + 4] cage depending on the solvent effect. Single-crystal structure analysis reveals that the caivity is surrounded by four phosphate uints. Good selectivity of CO(2) adsorption over CH(4) is demonstrated by the gas adsorption experiment. Nature Publishing Group UK 2020-03-13 /pmc/articles/PMC7070053/ /pubmed/32170278 http://dx.doi.org/10.1038/s41598-020-61813-6 Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Feng, Gen-Feng
Geng, Jiao
Feng, Fan-Da
Huang, Wei
Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage
title Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage
title_full Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage
title_fullStr Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage
title_full_unstemmed Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage
title_short Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage
title_sort solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070053/
https://www.ncbi.nlm.nih.gov/pubmed/32170278
http://dx.doi.org/10.1038/s41598-020-61813-6
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