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Direct Base-Assisted C‒H Cyclonickelation of 6-Phenyl-2,2′-bipyridine
The organonickel complexes [Ni(Phbpy)X] (X = Br, OAc, CN) were obtained for the first time in a direct base-assisted arene C(sp(2))–H cyclometalation reaction from the rather unreactive precursor materials NiX(2) and HPhbpy (6-phenyl-2,2′-bipyridine) or from the versatile precursor [Ni(HPhbpy)Br(2)]...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070369/ https://www.ncbi.nlm.nih.gov/pubmed/32102281 http://dx.doi.org/10.3390/molecules25040997 |