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Direct Base-Assisted C‒H Cyclonickelation of 6-Phenyl-2,2′-bipyridine

The organonickel complexes [Ni(Phbpy)X] (X = Br, OAc, CN) were obtained for the first time in a direct base-assisted arene C(sp(2))–H cyclometalation reaction from the rather unreactive precursor materials NiX(2) and HPhbpy (6-phenyl-2,2′-bipyridine) or from the versatile precursor [Ni(HPhbpy)Br(2)]...

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Detalles Bibliográficos
Autores principales:	Vogt, Nicolas, Sivchik, Vasily, Sandleben, Aaron, Hörner, Gerald, Klein, Axel
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070369/ https://www.ncbi.nlm.nih.gov/pubmed/32102281 http://dx.doi.org/10.3390/molecules25040997

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