Enantioselective Iron/Bisquinolyldiamine Ligand-Catalyzed Oxidative Coupling Reaction of 2-Naphthols

An iron-catalyzed asymmetric oxidative homo-coupling of 2-naphthols for the synthesis of 1,1′-Bi-2-naphthol (BINOL) derivatives is reported. The coupling reaction provides enantioenriched BINOLs in good yields (up to 99%) and moderate enantioselectivities (up to 81:19 er) using an iron-complex gener...

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Detalles Bibliográficos
Autores principales: Wu, Lin-Yang, Usman, Muhammad, Liu, Wen-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070846/
https://www.ncbi.nlm.nih.gov/pubmed/32075144
http://dx.doi.org/10.3390/molecules25040852

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7070846/
https://www.ncbi.nlm.nih.gov/pubmed/32075144
http://dx.doi.org/10.3390/molecules25040852

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