Size is Important: Artificial Catalyst Mimics Behavior of Natural Enzymes

Heavily substituted (R)-DTBM-SegPHOS is active in the asymmetric Pd(II)-catalyzed hydrogenation or C−O bond cleavage of α-pivaloyloxy-1-(2-furyl)ethanone, whereas (R)-SegPHOS fails to catalyze either of these transformations. An extensive network of C−H ··· H−C interactions provided by the heavily s...

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Detalles Bibliográficos
Autores principales: Chen, Jianzhong, Gridnev, Ilya D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7076558/
https://www.ncbi.nlm.nih.gov/pubmed/32193144
http://dx.doi.org/10.1016/j.isci.2020.100960

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7076558/
https://www.ncbi.nlm.nih.gov/pubmed/32193144
http://dx.doi.org/10.1016/j.isci.2020.100960

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