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Size is Important: Artificial Catalyst Mimics Behavior of Natural Enzymes
Heavily substituted (R)-DTBM-SegPHOS is active in the asymmetric Pd(II)-catalyzed hydrogenation or C−O bond cleavage of α-pivaloyloxy-1-(2-furyl)ethanone, whereas (R)-SegPHOS fails to catalyze either of these transformations. An extensive network of C−H ··· H−C interactions provided by the heavily s...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Elsevier
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7076558/ https://www.ncbi.nlm.nih.gov/pubmed/32193144 http://dx.doi.org/10.1016/j.isci.2020.100960 |