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Coordination‐Cage‐Catalysed Hydrolysis of Organophosphates: Cavity‐ or Surface‐Based?

The hydrophobic central cavity of a water‐soluble M(8)L(12) cubic coordination cage can accommodate a range of phospho‐diester and phospho‐triester guests such as the insecticide “dichlorvos” (2,2‐dichlorovinyl dimethyl phosphate) and the chemical warfare agent analogue di(isopropyl) chlorophosphate...

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Detalles Bibliográficos
Autores principales: Taylor, Christopher G. P., Metherell, Alexander J., Argent, Stephen P., Ashour, Fatma M., Williams, Nicholas H., Ward, Michael D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7079011/
https://www.ncbi.nlm.nih.gov/pubmed/31774202
http://dx.doi.org/10.1002/chem.201904708