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Nickel‐Catalyzed Anionic Cross‐Coupling Reaction of Lithium Sulfonimidoyl Alkylidene Carbenoids With Organolithiums

The mechanistic platform for a novel nickel(0)‐catalyzed anionic cross‐coupling reaction (ACCR) of lithium sulfonimidoyl alkylidene carbenoids (metalloalkenyl sulfoximines) with organometallic reagents is reported herein, affording substituted alkenylmetals and lithium sulfinamides. The Ni(0)‐cataly...

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Detalles Bibliográficos
Autores principales: Erdelmeier, Irene, Won, Joonghee, Park, Steve, Decker, Jürgen, Bülow, Gerd, Baik, Mu‐Hyun, Gais, Hans‐Joachim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7079181/
https://www.ncbi.nlm.nih.gov/pubmed/31667889
http://dx.doi.org/10.1002/chem.201904862