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Six-fold C–H borylation of hexa-peri-hexabenzocoronene

Hexa-peri-hexabenzocoronene (HBC) is known to be a poorly soluble polycyclic aromatic hydrocarbon for which direct functionalization methods have been very limited. Herein, the synthesis of hexaborylated HBC from unsubstituted HBC is described. Iridium-catalyzed six-fold C–H borylation of HBC was su...

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Detalles Bibliográficos
Autores principales: Nagase, Mai, Kato, Kenta, Yagi, Akiko, Segawa, Yasutomo, Itami, Kenichiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7082694/
https://www.ncbi.nlm.nih.gov/pubmed/32256855
http://dx.doi.org/10.3762/bjoc.16.37