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Electrophilic Reactivities of Vinyl p-Quinone Methides

[Image: see text] The electrophilic reactivity of a series of 8-arylated vinyl p-quinone methides (pVQMs) was determined by analyzing the kinetics of their reactions with carbanions in DMSO at 20 °C according to the linear free energy relationship log k = s(N)(N + E). The electrophilicity parameters...

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Detalles Bibliográficos
Autores principales: Eitzinger, Andreas, Mayer, Robert J., Hampel, Nathalie, Mayer, Peter, Waser, Mario, Ofial, Armin R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7091536/
https://www.ncbi.nlm.nih.gov/pubmed/32118449
http://dx.doi.org/10.1021/acs.orglett.0c00338