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Synthesis of six-membered silacycles by borane-catalyzed double sila-Friedel–Crafts reaction

We have developed a catalytic synthetic method to prepare phenoxasilins. A borane-catalyzed double sila-Friedel–Crafts reaction between amino group-containing diaryl ethers and dihydrosilanes can be used to prepare a variety of phenoxasilin derivatives in good to excellent yields. The optimized reac...

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Detalles Bibliográficos
Autores principales: Dong, Yafang, Sakai, Masahiko, Fuji, Kazuto, Sekine, Kohei, Kuninobu, Yoichiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7113548/
https://www.ncbi.nlm.nih.gov/pubmed/32273904
http://dx.doi.org/10.3762/bjoc.16.39