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Synthesis of six-membered silacycles by borane-catalyzed double sila-Friedel–Crafts reaction
We have developed a catalytic synthetic method to prepare phenoxasilins. A borane-catalyzed double sila-Friedel–Crafts reaction between amino group-containing diaryl ethers and dihydrosilanes can be used to prepare a variety of phenoxasilin derivatives in good to excellent yields. The optimized reac...
Autores principales: | Dong, Yafang, Sakai, Masahiko, Fuji, Kazuto, Sekine, Kohei, Kuninobu, Yoichiro |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7113548/ https://www.ncbi.nlm.nih.gov/pubmed/32273904 http://dx.doi.org/10.3762/bjoc.16.39 |
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