Iron-Catalyzed Asymmetric Hydrosilylation of Vinylcyclopropanes via Stereospecific C-C Bond Cleavage

An iron-catalyzed highly anti-Markovnikov selective, enantioselective hydrosilylation of vinylcyclopropanes with PhSiH(3) was reported for the preparation of valuable chiral allylic silanes via stereospecific C-C bond cleavage. Simultaneously, difficultly prepared chiral VCPs could be also obtained...

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Detalles Bibliográficos
Autores principales: Chen, Chenhui, Wang, Hongliang, Sun, Yufeng, Cui, Jiayan, Xie, Jianbo, Shi, Yang, Yu, Shijia, Hong, Xin, Lu, Zhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7115165/
https://www.ncbi.nlm.nih.gov/pubmed/32240952
http://dx.doi.org/10.1016/j.isci.2020.100985

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7115165/
https://www.ncbi.nlm.nih.gov/pubmed/32240952
http://dx.doi.org/10.1016/j.isci.2020.100985

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