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Iron-Catalyzed Asymmetric Hydrosilylation of Vinylcyclopropanes via Stereospecific C-C Bond Cleavage

An iron-catalyzed highly anti-Markovnikov selective, enantioselective hydrosilylation of vinylcyclopropanes with PhSiH(3) was reported for the preparation of valuable chiral allylic silanes via stereospecific C-C bond cleavage. Simultaneously, difficultly prepared chiral VCPs could be also obtained...

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Detalles Bibliográficos
Autores principales:	Chen, Chenhui, Wang, Hongliang, Sun, Yufeng, Cui, Jiayan, Xie, Jianbo, Shi, Yang, Yu, Shijia, Hong, Xin, Lu, Zhan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Elsevier 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7115165/ https://www.ncbi.nlm.nih.gov/pubmed/32240952 http://dx.doi.org/10.1016/j.isci.2020.100985

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