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Communication: Charge transfer dominates over proton transfer in the reaction of nitric acid with gas-phase hydrated electrons
The reaction of HNO(3) with hydrated electrons (H(2)O)(n) (−) (n = 35–65) in the gas phase was studied using Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry and ab initio molecular dynamics simulations. Kinetic analysis of the experimental data shows that OH(−)(H(2)O)(m) is form...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7116334/ https://www.ncbi.nlm.nih.gov/pubmed/28915744 http://dx.doi.org/10.1063/1.4999392 |