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Redox activity of a dissymmetric ligand bridging divalent ytter-bium and reactive nickel fragments†
The reaction of a reactive nickel dimethyl 1 bearing a redox-active, dissymmetric ligand, which is obtained by deprotonation of 2-pyrimidin-2-yl-1H-benzimidazole (Hbimpm) with a divalent lanthanide complex, Cp*(2)Yb(OEt(2)), affords an unprecedented, trimeric 2 with C(sp(3))–C(sp(3)) bond formation...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7116723/ https://www.ncbi.nlm.nih.gov/pubmed/33575034 http://dx.doi.org/10.1039/D0QI00952K |