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Redox activity of a dissymmetric ligand bridging divalent ytter-bium and reactive nickel fragments†

The reaction of a reactive nickel dimethyl 1 bearing a redox-active, dissymmetric ligand, which is obtained by deprotonation of 2-pyrimidin-2-yl-1H-benzimidazole (Hbimpm) with a divalent lanthanide complex, Cp*(2)Yb(OEt(2)), affords an unprecedented, trimeric 2 with C(sp(3))–C(sp(3)) bond formation...

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Detalles Bibliográficos
Autores principales:	Wang, Ding, Tricoire, Maxime, Cemortan, Valeriu, Moutet, Jules, Nocton, Grégory
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7116723/ https://www.ncbi.nlm.nih.gov/pubmed/33575034 http://dx.doi.org/10.1039/D0QI00952K

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