Electrophilic and nucleophilic pathways in ligand oxide mediated reactions of phenylsulfinylacetic acids with oxo(salen)chromium(V) complexes

The mechanism of oxidative decarboxylation of phenylsulfinylacetic acids (PSAA) by oxo(salen)Cr(V)(+) ion in the presence of ligand oxides has been studied spectrophotometrically in acetonitrile medium. Addition of ligand oxides (LO) causes a red shift in the λ(max) values of oxo(salen) complexes an...

Descripción completa

Detalles Bibliográficos
Autores principales: Subramaniam, P., Sugirtha Devi, S., Anbarasan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier Ltd. 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7116920/
https://www.ncbi.nlm.nih.gov/pubmed/32287835
http://dx.doi.org/10.1016/j.poly.2016.05.012

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7116920/
https://www.ncbi.nlm.nih.gov/pubmed/32287835
http://dx.doi.org/10.1016/j.poly.2016.05.012

Ejemplares similares