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Regioselectively α- and β-alkynylated BODIPY dyes via gold(I)-catalyzed direct C–H functionalization and their photophysical properties

A series of α- and β-ethynyl-substituted BODIPY derivatives (3a, 4a, 5a, 5b, 6a, 6b) were synthesized by gold(I)-catalyzed direct C–H alkynylation reactions of dipyrromethane and BODIPY, respectively, with ethynylbenziodoxolone (EBX) in a regioselective manner. Depending on the position of the ethyn...

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Detalles Bibliográficos
Autores principales: Shimada, Takahide, Mori, Shigeki, Ishida, Masatoshi, Furuta, Hiroyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7136566/
https://www.ncbi.nlm.nih.gov/pubmed/32280386
http://dx.doi.org/10.3762/bjoc.16.53