Sterically Regulated α-Oxygenation of α-Bromocarbonyl Compounds Promoted Using 2-Aryl-1,3-dimethylbenzimidazolines and Air

[Image: see text] A debrominative oxygenation protocol has been developed for the conversion of α-bromo-α,α-dialkyl-substituted carbonyl compounds to their corresponding α-hydroxy analogues. For example, stirring a solution of α-bromoisobutyrophenone and 2-aryl-1,3-dimethylbenzimidazoline (BIH-Ar) a...

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Detalles Bibliográficos
Autores principales: Hasegawa, Eietsu, Yoshioka, Naoki, Tanaka, Tsukasa, Nakaminato, Taisei, Oomori, Kazuki, Ikoma, Tadaaki, Iwamoto, Hajime, Wakamatsu, Kan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7144160/
https://www.ncbi.nlm.nih.gov/pubmed/32280909
http://dx.doi.org/10.1021/acsomega.0c00509

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7144160/
https://www.ncbi.nlm.nih.gov/pubmed/32280909
http://dx.doi.org/10.1021/acsomega.0c00509

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