Nucleophilic Substitution at Tetracoordinate Sulfur. Kinetics and Mechanism of the Chloride-Chloride Exchange Reaction in Arenesulfonyl Chlorides: Counterintuitive Acceleration of Substitution at Sulfonyl Sulfur by ortho-Alkyl Groups and Its Origin

The chloride-chloride exchange reaction in arenesulfonyl chlorides was investigated experimentally and theoretically by density functional theory (DFT) calculations. The second order rate constants and activation parameters of this identity reaction were determined for 22 variously substituted arene...

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Detalles Bibliográficos
Autores principales: Mikołajczyk, Marian, Gajl, Monika, Błaszczyk, Jarosław, Cypryk, Marek, Gostyński, Bartłomiej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7144404/
https://www.ncbi.nlm.nih.gov/pubmed/32245137
http://dx.doi.org/10.3390/molecules25061428

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7144404/
https://www.ncbi.nlm.nih.gov/pubmed/32245137
http://dx.doi.org/10.3390/molecules25061428

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