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A Relay Strategy Actuates Pre-Existing Trisubstituted Olefins in Monoterpenoids for Cross-Metathesis with Trisubstituted Alkenes
[Image: see text] A retrosynthetic disconnection–reconnection analysis of epoxypolyenes—substrates that can undergo cyclization to podocarpane-type tricycles—reveals relay-actuated Δ(6,7)-functionalized monoterpenoid alcohols for ruthenium benzylidene catalyzed olefin cross-metathesis with homopreny...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7145354/ https://www.ncbi.nlm.nih.gov/pubmed/32191466 http://dx.doi.org/10.1021/acs.joc.0c00067 |