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A Relay Strategy Actuates Pre-Existing Trisubstituted Olefins in Monoterpenoids for Cross-Metathesis with Trisubstituted Alkenes

[Image: see text] A retrosynthetic disconnection–reconnection analysis of epoxypolyenes—substrates that can undergo cyclization to podocarpane-type tricycles—reveals relay-actuated Δ(6,7)-functionalized monoterpenoid alcohols for ruthenium benzylidene catalyzed olefin cross-metathesis with homopreny...

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Detalles Bibliográficos
Autores principales: Bahou, Karim A., Braddock, D. Christopher, Meyer, Adam G., Savage, G. Paul, Shi, Zhensheng, He, Tianyou
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7145354/
https://www.ncbi.nlm.nih.gov/pubmed/32191466
http://dx.doi.org/10.1021/acs.joc.0c00067