An Improved P(III)/P(V)=O-Catalyzed Reductive C–N Coupling of Nitroaromatics and Boronic Acids by Mechanistic Differentiation of Rate- and Product-Determining Steps

[Image: see text] Experimental, spectroscopic, and computational studies are reported that provide an evidence-based mechanistic description of an intermolecular reductive C–N coupling of nitroarenes and arylboronic acids catalyzed by a redox-active main-group catalyst (1,2,2,3,4,4-hexamethylphosphe...

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Detalles Bibliográficos
Autores principales: Li, Gen, Nykaza, Trevor V., Cooper, Julian C., Ramirez, Antonio, Luzung, Michael R., Radosevich, Alexander T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7146866/
https://www.ncbi.nlm.nih.gov/pubmed/32178514
http://dx.doi.org/10.1021/jacs.0c01666

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7146866/
https://www.ncbi.nlm.nih.gov/pubmed/32178514
http://dx.doi.org/10.1021/jacs.0c01666

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