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Solid–State Molecular Organometallic Catalysis in Gas/Solid Flow (Flow-SMOM) as Demonstrated by Efficient Room Temperature and Pressure 1-Butene Isomerization

[Image: see text] The use of solid–state molecular organometallic chemistry (SMOM–chem) to promote the efficient double bond isomerization of 1-butene to 2-butenes under flow–reactor conditions is reported. Single crystalline catalysts based upon the σ-alkane complexes [Rh(R(2)PCH(2)CH(2)PR(2))(η(2)...

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Detalles Bibliográficos
Autores principales: Martínez-Martínez, Antonio J., Royle, Cameron G., Furfari, Samantha K., Suriye, Kongkiat, Weller, Andrew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7147255/
https://www.ncbi.nlm.nih.gov/pubmed/32296595
http://dx.doi.org/10.1021/acscatal.9b03727