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Solid–State Molecular Organometallic Catalysis in Gas/Solid Flow (Flow-SMOM) as Demonstrated by Efficient Room Temperature and Pressure 1-Butene Isomerization
[Image: see text] The use of solid–state molecular organometallic chemistry (SMOM–chem) to promote the efficient double bond isomerization of 1-butene to 2-butenes under flow–reactor conditions is reported. Single crystalline catalysts based upon the σ-alkane complexes [Rh(R(2)PCH(2)CH(2)PR(2))(η(2)...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7147255/ https://www.ncbi.nlm.nih.gov/pubmed/32296595 http://dx.doi.org/10.1021/acscatal.9b03727 |