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Synthesis of a Mechanically Planar Chiral Rotaxane Ligand for Enantioselective Catalysis

Rotaxanes are interlocked molecules in which a molecular ring is trapped on a dumbbell-shaped axle because of its inability to escape over the bulky end groups, resulting in a so-called mechanical bond. Interlocked molecules have mainly been studied as components of molecular machines, but the crowd...

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Detalles Bibliográficos
Autores principales: Heard, Andrew W., Goldup, Stephen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7153771/
https://www.ncbi.nlm.nih.gov/pubmed/32309674
http://dx.doi.org/10.1016/j.chempr.2020.02.006