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Synthesis of a Mechanically Planar Chiral Rotaxane Ligand for Enantioselective Catalysis
Rotaxanes are interlocked molecules in which a molecular ring is trapped on a dumbbell-shaped axle because of its inability to escape over the bulky end groups, resulting in a so-called mechanical bond. Interlocked molecules have mainly been studied as components of molecular machines, but the crowd...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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Elsevier
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7153771/ https://www.ncbi.nlm.nih.gov/pubmed/32309674 http://dx.doi.org/10.1016/j.chempr.2020.02.006 |