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Tetraiododiborane(4) (B(2)I(4)) is a Polymer Based on sp(3) Boron in the Solid State

Herein we present the first solid‐state structures of tetraiododiborane(4) (B(2)I(4)), which was long believed to exist in all phases as discrete molecules with planar, tricoordinate boron atoms, like the lighter tetrahalodiboranes(4) B(2)F(4), B(2)Cl(4), and B(2)Br(4). Single‐crystal X‐ray diffract...

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Detalles Bibliográficos
Autores principales: Muessig, Jonas H., Lisinetskaya, Polina, Dewhurst, Rian D., Bertermann, Rüdiger, Thaler, Melanie, Mitrić, Roland, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154622/
https://www.ncbi.nlm.nih.gov/pubmed/31840333
http://dx.doi.org/10.1002/anie.201913590