Tandem Acid/Pd‐Catalyzed Reductive Rearrangement of Glycol Derivatives

Herein, we describe the acid/Pd‐tandem‐catalyzed transformation of glycol derivatives into terminal formic esters. Mechanistic investigations show that the substrate undergoes rearrangement to an aldehyde under [1,2] hydrogen migration and cleavage of an oxygen‐based leaving group. The leaving group...

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Detalles Bibliográficos
Autores principales: Schmidt, Tanno A., Ciszek, Benjamin, Kathe, Prasad, Fleischer, Ivana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154628/
https://www.ncbi.nlm.nih.gov/pubmed/31951298
http://dx.doi.org/10.1002/chem.202000251

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154628/
https://www.ncbi.nlm.nih.gov/pubmed/31951298
http://dx.doi.org/10.1002/chem.202000251

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