An Adaptable N‐Heterocyclic Carbene Macrocycle Hosting Copper in Three Oxidation States

A neutral hybrid macrocycle with two trans‐positioned N‐heterocyclic carbenes (NHCs) and two pyridine donors hosts copper in three oxidation states (+I–+III) in a series of structurally characterized complexes (1–3). Redox interconversion of [LCu](+/2+/3+) is electrochemically (quasi)reversible and...

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Detalles Bibliográficos
Autores principales: Liu, Yang, Resch, Stefan G., Klawitter, Iris, Cutsail, George E., Demeshko, Serhiy, Dechert, Sebastian, Kühn, Fritz E., DeBeer, Serena, Meyer, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154638/
https://www.ncbi.nlm.nih.gov/pubmed/31769151
http://dx.doi.org/10.1002/anie.201912745

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154638/
https://www.ncbi.nlm.nih.gov/pubmed/31769151
http://dx.doi.org/10.1002/anie.201912745

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