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An Adaptable N‐Heterocyclic Carbene Macrocycle Hosting Copper in Three Oxidation States
A neutral hybrid macrocycle with two trans‐positioned N‐heterocyclic carbenes (NHCs) and two pyridine donors hosts copper in three oxidation states (+I–+III) in a series of structurally characterized complexes (1–3). Redox interconversion of [LCu](+/2+/3+) is electrochemically (quasi)reversible and...
Autores principales: | Liu, Yang, Resch, Stefan G., Klawitter, Iris, Cutsail, George E., Demeshko, Serhiy, Dechert, Sebastian, Kühn, Fritz E., DeBeer, Serena, Meyer, Franc |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154638/ https://www.ncbi.nlm.nih.gov/pubmed/31769151 http://dx.doi.org/10.1002/anie.201912745 |
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