Photoinduced Proton‐Transfer Reactions for Mild O‐H Functionalization of Unreactive Alcohols

Hexafluoroisopropanol is typically considered as an unreactive solvent and not as a reagent in organic synthesis. Herein, we report on a mild and efficient photochemical reaction of aryl diazoacetates with hexafluoroisopropanol that enables, under stoichiometric reaction conditions, the synthesis of...

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Detalles Bibliográficos
Autores principales: Jana, Sripati, Yang, Zhen, Li, Fang, Empel, Claire, Ho, Junming, Koenigs, Rene M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154649/
https://www.ncbi.nlm.nih.gov/pubmed/31880397
http://dx.doi.org/10.1002/anie.201915161

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154649/
https://www.ncbi.nlm.nih.gov/pubmed/31880397
http://dx.doi.org/10.1002/anie.201915161

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