Synthesis and Reactivity of the First Isolated Hydrogen‐Bridged Silanol–Silanolate Anions

We report on the first examples of isolated silanol–silanolate anions, obtained by utilizing weakly coordinating phosphazenium counterions. The silanolate anions were synthesized from the recently published phosphazenium hydroxide hydrate salt with siloxanes. The silanol–silanolate anions are postul...

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Detalles Bibliográficos
Autores principales: Weitkamp, Robin F., Neumann, Beate, Stammler, Hans‐Georg, Hoge, Berthold
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154667/
https://www.ncbi.nlm.nih.gov/pubmed/31833629
http://dx.doi.org/10.1002/anie.201914339

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154667/
https://www.ncbi.nlm.nih.gov/pubmed/31833629
http://dx.doi.org/10.1002/anie.201914339

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