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Catechol Thioesters: Ligands for Hierarchically Formed Lithium‐Bridged Titanium(IV) Helicates and Helicate‐Based Switches

The thioester moiety is introduced as a lithium binding unit for the hierarchical formation of titanium(IV) catecholate‐based lithium‐bridged helicates. In solution, the coordination compounds show a monomer–dimer equilibrium which —in comparison to the oxo esters— is significantly shifted towards t...

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Detalles Bibliográficos
Autores principales: Kwamen, A. Carel N., de Macedo, Gilles S., Wiederhold, Constanze, Oppel, Iris M., Albrecht, Markus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154688/
https://www.ncbi.nlm.nih.gov/pubmed/31899932
http://dx.doi.org/10.1002/chem.201905212