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Heterobifunctional Rotaxanes for Asymmetric Catalysis

Heterobifunctional rotaxanes serve as efficient catalysts for the addition of malonates to Michael acceptors. We report a series of four different heterobifunctional rotaxanes, featuring an amine‐based thread and a chiral 1,1′‐binaphthyl‐phosphoric‐acid‐based macrocycle. High‐level DFT calculations...

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Detalles Bibliográficos
Autores principales: Pairault, Noël, Zhu, Hui, Jansen, Dennis, Huber, Alexander, Daniliuc, Constantin G., Grimme, Stefan, Niemeyer, Jochen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154720/
https://www.ncbi.nlm.nih.gov/pubmed/31793163
http://dx.doi.org/10.1002/anie.201913781