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Heterobifunctional Rotaxanes for Asymmetric Catalysis

Heterobifunctional rotaxanes serve as efficient catalysts for the addition of malonates to Michael acceptors. We report a series of four different heterobifunctional rotaxanes, featuring an amine‐based thread and a chiral 1,1′‐binaphthyl‐phosphoric‐acid‐based macrocycle. High‐level DFT calculations...

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Detalles Bibliográficos
Autores principales:	Pairault, Noël, Zhu, Hui, Jansen, Dennis, Huber, Alexander, Daniliuc, Constantin G., Grimme, Stefan, Niemeyer, Jochen
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154720/ https://www.ncbi.nlm.nih.gov/pubmed/31793163 http://dx.doi.org/10.1002/anie.201913781

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