A Spherically Shielded Triphenylamine and Its Persistent Radical Cation

This work reports the design and synthesis of a sterically protected triphenylamine scaffold which undergoes one‐electron oxidation to form an amine‐centered radical cation of remarkable stability. Several structural adjustments were made to tame the inherent reactivity of the radical cation. First,...

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Detalles Bibliográficos
Autores principales: Schaub, Tobias A., Mekelburg, Theresa, Dral, Pavlo O., Miehlich, Matthias, Hampel, Frank, Meyer, Karsten, Kivala, Milan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154785/
https://www.ncbi.nlm.nih.gov/pubmed/31970834
http://dx.doi.org/10.1002/chem.202000355

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154785/
https://www.ncbi.nlm.nih.gov/pubmed/31970834
http://dx.doi.org/10.1002/chem.202000355

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