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A Spherically Shielded Triphenylamine and Its Persistent Radical Cation
This work reports the design and synthesis of a sterically protected triphenylamine scaffold which undergoes one‐electron oxidation to form an amine‐centered radical cation of remarkable stability. Several structural adjustments were made to tame the inherent reactivity of the radical cation. First,...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154785/ https://www.ncbi.nlm.nih.gov/pubmed/31970834 http://dx.doi.org/10.1002/chem.202000355 |